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Zeta100電位納米粒度分子量分析儀是測量電勢(shì)的儀器

更新時(shí)間：2025-10-30

點(diǎn)擊次數(shù)：1921

　　Zeta100電位納米粒度分子量分析儀是測量電勢(shì)的儀器，Zeta電位是液體中懸浮的粒子很接近表面位置的靜電勢(shì)1。Zeta電位（ζ）是由膠體中粒子與粒子間的相互作用造成的，因此它可以用來預(yù)測膠體體系里粒子聚集的穩(wěn)定性。

在水相介質(zhì)中，Zeta電位通常是由于粒子表面的離子離解而產(chǎn)生的，在表面附近留下一個(gè)被反離子云包圍的凈電荷。各種類型的離子可以通過滑動(dòng)面擴(kuò)散進(jìn)來和出去，滑動(dòng)面允許Zeta電位根據(jù)液體中的離子組成而變化，例如pH值。離子也可以通過參與滑動(dòng)面內(nèi)的化學(xué)反應(yīng)，從而影響Zeta電位。

　　雙電層的厚度與溶液中的離子濃度有關(guān)，可根據(jù)介質(zhì)的離子強(qiáng)度進(jìn)行計(jì)算，離子強(qiáng)度越高，雙電層愈壓縮同，離子的化合價(jià)也會(huì)影響雙單層的厚度，三價(jià)離子（Al3＋）將會(huì)比單價(jià)離子（Na＋）更多的壓縮雙電層。

　　Stern層為吸附在顆粒表面的一層電荷組成的一個(gè)緊密層，由顆粒表面到Stern層平面的電位呈現(xiàn)下降的趨勢(shì)，降到緊密層時(shí)的電位稱為Stern電位。Stern層外異號(hào)離子成擴(kuò)散狀態(tài)分布，稱為擴(kuò)散層。

　　當(dāng)施加外界電場時(shí)，顆粒做電泳運(yùn)動(dòng)，緊密層結(jié)合一定的內(nèi)部擴(kuò)散層與分散介質(zhì)發(fā)生相對(duì)移動(dòng)時(shí)的界面稱為滑動(dòng)面。顆粒表面電位降到滑動(dòng)面時(shí)的電位稱為Zeta電位，即Zeta電位是連續(xù)相與附著在分散粒子上的流體穩(wěn)定層之間的電勢(shì)差。

　　計(jì)算出的Zeta電位取決于這些計(jì)算中使用的理論，即粒子遷移率與Zeta電位的關(guān)系。另一種測量大顆?；虮砻骐娢坏姆椒ㄊ菍⒁后w移到靜止的顆粒、纖維或表面上，然后測量產(chǎn)生的流動(dòng)電位。

　　分散體系的Zeta電位可因下列因素而變化：

　　1、pH的變化

　　2、溶液電導(dǎo)率的變化

　　3、某種特殊添加劑的濃度，如表面活性劑，高分子

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