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使用表面張力儀能做些什么事？

更新時(shí)間：2022-02-15

點(diǎn)擊次數(shù)：1674

　　表面張力儀適合于離子表面活性劑和非離子表面活性劑臨界膠束濃度的測定，無機(jī)離子的存在也不影響測定結(jié)果。在表面活性劑濃度較低時(shí)，隨著濃度的增加，溶液的表面張力急劇下降，當(dāng)?shù)竭_(dá)臨界膠束濃度時(shí)，表面張力的下降則很緩慢或停止。

　　以表面張力對表面活性劑濃度的對數(shù)作圖，曲線轉(zhuǎn)折點(diǎn)相對應(yīng)的濃度即為CMC。如果在表面活性劑中或溶液中含有少量長鏈醇、高級胺、脂肪酸等高表面活性的極性有機(jī)物時(shí)，溶液的表面張力-濃度對數(shù)曲線上的轉(zhuǎn)折可能變得不明顯，但出現(xiàn)一個(gè)低值。這也是用以鑒別表面活性劑純度的方法之一。

　　電導(dǎo)法本法僅適合于表面活性較強(qiáng)的離子表面活性劑CMC的測定，以表面活性劑溶液。電導(dǎo)率或摩爾電導(dǎo)率對濃度或濃度的平方根作圖，曲線的轉(zhuǎn)折點(diǎn)即CMC。溶液中若含有無機(jī)離子時(shí)，方法的靈敏度大大下降。

　　我們生活中經(jīng)常會(huì)跟表面張力打交道，卻清楚認(rèn)知它。它在清潔洗滌中扮演者象汽車、化妝品中的潤滑劑那樣的角色。水甲蟲之所以不被淹死只不過是因?yàn)楸砻鎻埩υ谧鞴?。液體中分子之間的吸引力是產(chǎn)生表面張力的原因。如果我們觀察某種介質(zhì)的內(nèi)部分子結(jié)構(gòu)的時(shí)候，會(huì)發(fā)現(xiàn)分子間的吸引力是相同的。

　　因此，分子所受到的各個(gè)方向的力是相同的，合力為零。另一方面，如果分子處于液體表面，液體內(nèi)部的吸引力作用在一邊，另外一邊卻沒有分子作用力的存在。因此，合力的方向是指向液體內(nèi)部的。從宏觀來看，液體表面積會(huì)趨向最小化，液滴將因此趨向變圓。

　　使用表面張力儀研究表面張力主要是為了確定：

　　1、液體的自身性質(zhì)；

　　2、環(huán)境對表面張力的影響；

　　3、具有特殊功能的活性劑的濃度。

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